碳一化學(xué)前瞻性文章

大連化物所催化基礎(chǔ)國(guó)家重點(diǎn)實(shí)驗(yàn)室鄧德會(huì)研究員、包信和院士團(tuán)隊(duì)在碳一分子催化轉(zhuǎn)化方面的研究工作引起國(guó)內(nèi)外同行的廣泛關(guān)注。近日，該團(tuán)隊(duì)受邀發(fā)表了題為“Catalysis for Selected C1 Chemistry”的前瞻性文章。
The research work of Deng Dehui, a researcher in the State Key Laboratory of Catalysis Foundation of Dalian Institute of Chemical Physics, and Bao Xinhe, an academician team, in the field of carbon molecule catalytic conversion has attracted extensive attention from peers at home and abroad. Recently, the team was invited to publish a prospective article titled "Catalysis for Selected C1 Chemistry".
全球化石資源的逐漸消耗帶來(lái)了日益嚴(yán)峻的環(huán)境污染問題，尋求低碳排放且高效轉(zhuǎn)化碳一分子（CH4、CO2、CO、CH3OH等）為燃料或高值化學(xué)品的途徑尤為重要。然而，由于碳一分子的化學(xué)性質(zhì)差異大，如CH4、CO2等相對(duì)惰性；CH3OH、CO等相對(duì)活潑，在平衡轉(zhuǎn)化率和選擇性等方面存在一定的限制。目前工業(yè)上的碳一轉(zhuǎn)化過(guò)程存在能耗高、步驟多、產(chǎn)品分離工藝復(fù)雜等問題。因此，探索溫和條件下碳一分子定向轉(zhuǎn)化技術(shù)是一個(gè)迫切但又極具挑戰(zhàn)的課題。
The gradual consumption of global fossil resources has brought increasingly severe environmental pollution problems, and it is particularly important to seek low-carbon emissions and efficient ways to convert carbon molecules (CH4, CO2, CO, CH3OH, etc.) into fuels or high-value chemicals. However, due to the significant differences in chemical properties of carbon molecules, such as CH4, CO2, etc., they are relatively inert; CH3OH, CO, etc. are relatively active and have certain limitations in terms of equilibrium conversion rate and selectivity. At present, the industrial carbon one conversion process has problems such as high energy consumption, multiple steps, and complex product separation processes. Therefore, exploring the technology of carbon one molecule directed conversion under mild conditions is an urgent but highly challenging topic.
該文章系統(tǒng)評(píng)述了該研究團(tuán)隊(duì)與國(guó)際同行近十年來(lái)在碳一分子轉(zhuǎn)化方面的最新進(jìn)展和重要突破，特別關(guān)注了新的催化反應(yīng)過(guò)程，包括溫和條件下的熱催化、電催化、光催化轉(zhuǎn)化過(guò)程，以及多能耦合催化轉(zhuǎn)化過(guò)程等，并詳細(xì)討論了碳一催化化學(xué)的關(guān)鍵挑戰(zhàn)及未來(lái)發(fā)展方向。
This article systematically reviews the latest progress and important breakthroughs of the research team and international peers in the conversion of carbon one molecules in the past decade, with a particular focus on new catalytic reaction processes, including thermal catalysis, electrocatalysis, photocatalytic conversion under mild conditions, and multi energy coupling catalytic conversion processes. It also discusses in detail the key challenges and future development directions of carbon one catalytic chemistry.
 
鄧德會(huì)和包信和團(tuán)隊(duì)致力于碳一分子的催化轉(zhuǎn)化方面的研究工作并取得了系列進(jìn)展，包括甲烷室溫氧化制含氧化合物（Chem, 2018, 4, 1902），室溫電化學(xué)水氣變換制高純氫（Nat. Commun., 2019, 10, 86），電催化CO還原制乙烯（Angew. Chem. Int. Ed., 2020, 59, 154）、電催化CO2還原制CO（Angew. Chem. Int. Ed., 2018, 57, 16339）、可見光驅(qū)動(dòng)的甲醇直接制乙二醇（Nat. Commun., 2018, 9, 1181）等，為C1化學(xué)催化新過(guò)程、新體系的探索提供了重要借鑒。
Deng Dehui and Bao Xinhe's team are dedicated to the research work of catalytic conversion of carbon one molecule and have made a series of progress, including the room temperature oxidation of methane to oxygen-containing compounds (Chem, 2018, 4, 1902), room temperature electrochemical water gas shift to high-purity hydrogen (Nat. Commun., 2019, 10, 86), electrocatalytic CO reduction to ethylene (Angew. Chem. Int. Ed., 2020, 59, 154), electrocatalytic CO2 reduction to CO (Angew. Chem. Int. Ed., 2018, 57, 16339), visible light driven direct methanol to ethylene glycol (Nat. Commun., 2018, 9, 1181), etc., which are new processes and innovations in C1 chemical catalysis. The exploration of the system provides important references.
相關(guān)工作發(fā)表在《化學(xué)》（Chem）上。上述工作得到國(guó)家科技部重點(diǎn)研發(fā)計(jì)劃、國(guó)家自然科學(xué)基金重大項(xiàng)目、中科院前沿科學(xué)重點(diǎn)研究項(xiàng)目、中科院潔凈能源創(chuàng)新研究院合作基金等項(xiàng)目的資助。（文/圖 劉艷廷、高鶴華）
The relevant work was published in the journal Chem. The above work has been supported by the Key Research and Development Program of the Ministry of Science and Technology of China, the Major Project of the National Natural Science Foundation of China, the Key Research Project of Frontier Science of the Chinese Academy of Sciences, and the Cooperation Fund of the Clean Energy Innovation Research Institute of the Chinese Academy of Sciences. (Text/Picture: Liu Yanting, Gao Hehua)